𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of brownian diffusion on chemical kinetics

✍ Scribed by M. Sitarski

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
432 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A new method of theoretical prediction of the kinetic rate constants of fast chemical reactions in solutions is presented. It takes into account the effect of finite diffusive displacements of the reacting molecules. The approach is based on the solution of the steady‐state Fokker–Planck equation by the moments method of Grad developed in the theory of coagulation of aerosol particles. A comparison of the predicted rate constants with the experimental data provided by Schuh and Fischer for the self‐reaction of tert‐butyl radicals in n‐alkanes shows a good correspondence.

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