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Effective rotational Hamiltonian for PH3

✍ Scribed by Kamil Sarka


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
108 KB
Volume
151
Category
Article
ISSN
0022-2852

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Effective rotational Hamiltonian of the
✍ Qing-shi Zhu πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 384 KB

The effective rotational Hamiltonians of the local mode states are derived for XY,, XY, and XY4 molecules by averaging the vibration-rotation Hamiltonians using the corresponding local mode vibrational wavefunctions. The results indicate that in a local mode vibrational state the molecular symmetry