✍ Scribed by Marcin Molski
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to 15 unconstrained and 2 constrained parameters with s P Å 1.098, s Å 0.000554 cm 01 , and F Å 7.704 1 10 14 . The quality of the Born-Oppenheimer approximation and the extent of its breakdown in LiH are reexamined.
📜 SIMILAR VOLUMES
A deformationally self-consistent procedure and new expansion of the internuclear potential energy are applied to reduce the wavenumbers of 727 pure rotational and vibration-rotational transitions of nine isotopic variants of GeS to seven radial parameters with ˆϭ 1.048, ϭ 0.00015 cm Ϫ1 and F ϭ 1.32
The potential model of G. Thompson et al. [J. Mol. Spectrosc. 124, 130-138 (1987)] for an analysis of the vibrational-rotational and the rotational spectra of diatomic molecules is modified by an algebraic WKB treatment of the Schro ¨dinger equation given by Watson's effective Hamiltonian. A compact
The deformable-body model and a deformational self-consistent procedure are applied in the quantitative analysis of adiabatic and nonadiabatic effects in the vibration-rotational spectra of GaH X 1 S / . By making use of 18 independent unconstrained parameters 1094 vibration-rotational transitions o