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Application of Deformational Self-Consistent Procedure and New Potential Expansion to Effective Reduction of Wavenumbers of Rotational and Vibration–Rotational Transitions of GeSX1Σ+

✍ Scribed by Marcin Molski

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 84 KB
Volume: 193
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1998.7748

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✦ Synopsis

A deformationally self-consistent procedure and new expansion of the internuclear potential energy are applied to reduce the wavenumbers of 727 pure rotational and vibration-rotational transitions of nine isotopic variants of GeS to seven radial parameters with ˆϭ 1.048, ϭ 0.00015 cm Ϫ1 and F ϭ 1.32 ϫ 10 15 . A potential energy is expanded into a series of the variable ϭ (R Ϫ R 0 )/[aR ϩ (1 Ϫ a) R 0 ] with a treated as a free-fitted parameter. For GeS, we evaluated a ϭ 1.09255(81). This new expansion includes those of Dunham, Simons-Parr-Finlan, and Ogilvie as special cases corresponding to a ϭ 0, 1, 1 2 .

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