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Effective Hamiltonian for degenerate vibrational states in symmetric top molecules

✍ Scribed by Š. Urban; D. Papoušek; M. Garcia Hernandez


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
841 KB
Volume
124
Category
Article
ISSN
0022-2852

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Coordinates, Hamiltonian, and Symmetry O
✍ Jon T. Hougen 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 241 KB

Motivated by attempts to understand the mechanism(s) by which internal rotation of methyl tops strongly enhances intramolecular vibrational energy redistribution, a vibration-torsion-rotation Hamiltonian has been constructed for molecules containing one C 3£ rotor. Internal rotation is taken to be s