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Effective Chiral Thiophene Diamine Derivatives in Pd-Catalyzed Enantioselective Allylic Alkylation.

✍ Scribed by Sang-Han Kim; Eun-Kyung Lee; Geon-Joong Kim

Publisher
John Wiley and Sons
Year
2004
Weight
19 KB
Volume
35
Category
Article
ISSN
0931-7597

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Effective Chiral Ferrocenyl Phosphine-Th
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## Abstract magnified image Chiral ferrocene‐derived phosphine‐thioether mixed donor ligands supported by heterocycles effected the palladium‐catalyzed enantioselective allylic alkylations with excellent yields and enantioselectivities (up to 96% __ee__). With cyclic and unsymmetrical allylic acet