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Effect of zirconium addition on vanadium-catalyzed toluene oxidation by H2O2 in CH3COOH

✍ Scribed by Xueqin Wang; Xiuli Cao; Xiaoke Hu; Guiying Li; Liangfang Zhu; Changwei Hu


Book ID
113803615
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
843 KB
Volume
357
Category
Article
ISSN
1381-1169

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Oxidation of CH3NH2 and (CH3)2NH by NiII
✍ Dror Shamir; Israel Zilbermann; Eric Maimon; Dan Meyerstein πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 121 KB

## Abstract Ni^II^(1,4,8,11‐tetraazacyclotetradecane)^2+^, Ni^II^L^2+^, is a good electrocatalyst for the oxidation of CH~3~NH~2~ and (CH~3~)~2~NH but not of (CH~3~)~3~N. The oxidation kinetics of the amines by Ni^III^L(H~2~O)~2~^3+^ indicate that the amines are good axial ligands to the tervalent