Effect of vibrational excitation on the reactivity of methyl fluoride with bromine atoms
โ Scribed by Strunin, V. P. ;Serdyuk, N. K. ;Chesnokov, E. N. ;Panfilov, V. N.
- Book ID
- 112684796
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 180 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0133-1736
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Abstractionof bensylic hydrogenatoms Qyatomic bromine (fromCbroam succiniaide)~ndtgrthetrichloroathyl~dical, fmmbenzyl s&b1 ether (I,B-H)andbemaldehyde dimsthylacetal (I,R-0%) has recently teen shown1 to proceed by the follwzlng nmchanism:-Ph.CHR.(Olb) + Br\* (or4C13) + Ph.k(OMs)
The hydrogen fluoride infrared chemiluminescence produced by the reactions of fluorine atoms with cyclopropane, cyclopentane, and cyclohexane have been studied. The emission data were used to determine the vibrational energy distributions for the abstraction of hydrogen from the secondary carbon-hyd