✦ LIBER ✦

Effect of the type of monomers of molecularly imprinted polymers on the interaction with steroids

✍ Scribed by K. Sreenivasan

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 275 KB
Volume: 68
Category: Article
ISSN: 0021-8995
DOI: 10.1002/(sici)1097-4628(19980613)68:11<1863::aid-app18>3.0.co;2-v

No coin nor oath required. For personal study only.

✦ Synopsis

The recognition ability of molecularly imprinted polymers (MIPs) is largely governed by factors such as polymerization conditions, nature of crosslinking agents, and degree of crosslinking. In addition to these factors, monomers could also influence the ability of the MIPs to recognize the print molecules. MIPs based on 2-hydroxy ethyl methacrylate and N-vinyl pyrolidone imprinted for cholesterol and testosterone are prepared. The results show that the recognition ability strongly depends on the characteristics of monomer also, in addition to the nature of the print molecule.

📜 SIMILAR VOLUMES

The rational use of hydrophobic effect-b

The rational use of hydrophobic effect-based recognition in molecularly imprinted polymers

✍ Sergey A. Piletsky; Håkan S. Andersson; Ian A. Nicholls 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 179 KB 👁 1 views

A novel molecularly imprinted polymer (MIP) system selective for D-phenylalanine is described where polymerization is performed in aqueous solution. The unique polymer system comprises a hydrophobic moiety-selective functional monomer, polymerizable b-cyclodextrin, an electrostatic interacting funct

Solvent effect on the interaction of ste

Solvent effect on the interaction of steroids with a novel methyl β-cyclodextrin polymer

✍ K. Sreenivasan 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 275 KB 👁 1 views

Methyl b-cyclodextrin was modified by coupling 2-hydroxyethyl methacrylate using hexamethylene diisocyanate as the coupling agent. The methyl b-cyclodextrin-coupled monomer was polymerized thermally using azobisisobutyronitrile as the initiator. The new polymer is insoluble in water and organic solv

The use of metal-containing monomer in t

The use of metal-containing monomer in the preparation of molecularly imprinted polymer to increase the adsorption capacity

✍ K. Sreenivasan 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB

Effects of Dopant Concentration on the M

Effects of Dopant Concentration on the Mobilities of Molecularly Doped Polymers

✍ W. T. Gruenbaum; L.-B. Lin; E. H. Magin; P. M. Borsenberger 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 1 views

On the interaction mechanism of radical

On the interaction mechanism of radical photoinitiators with monomers

✍ V. Lemee; D. Burget; P. Jacques; J. P. Fouassier 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 1 views

Rate constants of quenching of triplet excited ketones by several monomers were determined through time-resolved laser spectroscopy or culled from the literature. The semi-empirical calculation method PM3 allows the quenching mechanisms to be refined and can be used to predict the reactivity of arom

Temperature effect on chiral recognition

Temperature effect on chiral recognition of some amino acids with molecularly imprinted polymer filled capillary electrochromatography

✍ Jin-Ming Lin; Tatsuro Nakagama; Katsumi Uchiyama; Toshiyuki Hobo 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

L-Aromatic amino acid imprinted polymers were prepared using azobisnitriles as either photoinitiators or thermal initiators at temperature ranging from 4 to 60ЊC. Methacrylic acid (MAA) was used as functional monomer and ethylene glycol dimethacrylate (EDMA) was used as cross-linker. The result poly