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Effect of the structure of complex-forming additives on radical exchange between phenyllithium and bromobenzene

โœ Scribed by A. P. Batalov

Book ID
112386429
Publisher
Springer
Year
1994
Tongue
English
Weight
310 KB
Volume
43
Category
Article
ISSN
1573-9171

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NMR studies on the ligand exchange react
NMR studies on the ligand exchange reactions between diaryl tellurides and phenyllithium: Detection of hypervalent triaryl tellurium ate complexes
โœ Satoshi Ogawa; Yutaka Masutomi; Naomichi Furukawa; Tomoki Erata ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 550 KB

Diaryl tellurides undergo rapid Iigand exchange and disproportionation reactions on treatment with phenyllithium at -78ยฐC. Triaryltelluranes [lo-Te-3(C,)]-Li were identified as discrete intermediates during the reactions by '"Te, ' H , I3C, and CH-COSY N M R studies.