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Effect of the structure of coal-related model ethers on the rate and mechanism of their thermolysis. 4. Effect of end groups in the C6H5CH2OR structure

✍ Scribed by Vjacheslav Yu. Korobkov; Evgeniya N. Grigorieva; Victor I. Bykov; Igor V. Kalechits

Book ID
107756391
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
406 KB
Volume
68
Category
Article
ISSN
0016-2361

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Effect of the structure of coal-related
Effect of the structure of coal-related model ethers on the rate and mechanism of their thermolysis: 1. Effect of the number of methylene groups in the R (CH2)nO(CH2)mR structure
✍ Vjacheslav Yu. Korobkov; Evgenija N. Grigorieva; Victor I. Bykov; Oleg V. Senko; 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 627 KB

The constants of thermolysis rate of C,H,~(CH,),~O~(CH,),-C6HS ethers were measured in conditions close to those of coal liquefaction (hydrogen pressure of 8.5 MPa; temperature up to 410°C) but minimizing secondary conversions (i.e. in ten-fold excess of tetralin). The ethers form the following reac