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Effect of the structure and concentration of diphosphine ligands on the rate of hydrocarbomethoxylation of cyclohexene catalyzed by palladium acetate/diphosphine/TsOH system

✍ Scribed by I.E. Nifant’ev; S.A. Batashev; S.A. Toloraya; A.N. Tavtorkin; N.T. Sevostyanova; A.A. Vorobiev; V.V. Bagrov; V.A. Averyanov


Book ID
113803562
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
370 KB
Volume
350
Category
Article
ISSN
1381-1169

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## Abstract We present the first systematic study of the Pd‐catalyzed asymmetric methoxycarbonylation of styrene in the presence of chiral ferrocenyl phosphine ligands. The reaction conditions were optimized, and a screening of different catalyst precursors was performed. A number of 1,1′‐bis(phosp