Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Olefins by Palladium−Diphosphine Catalysis
✍ Scribed by Bianchini, Claudio; Lee, Hon Man; Meli, Andrea; Oberhauser, Werner; Peruzzini, Maurizio; Vizza, Francesco
- Book ID
- 126820030
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 253 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0276-7333
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Enantioselective alternating copolymerization of carbon monoxide with propylene, 1-heptene, 1-octene, and styrene was carried out using a palladium catalyst modified by 1,4-3,6-dianhydro-2,5-dideoxy-2,5-bis(diphenylphosphino)-L-iditol (DDPPI). The pure poly(1,4-ketone)s were obtained by dissolving t
A series of styrene derivatives were synthesized from aromatic substances by Friedel-Crafts acylation, reduction, and dehydration. Alternating copolymers of styrene derivatives and carbon monoxide were prepared in the presence of a palladium(II) catalyst. The characterization of the polyketones prod