The use of organic solvents in the oxidation of I-dodecanethiol, catalyzed by cobalt( II) phthalocyanine-tetrasodiumsulfonate (CoPc(NaSO,),) /2,4-ionene, drastically influences the reaction mechanism. Without an organic solvent the reaction proceeds at the thiol-water phase boundary, where the ionen
Effect of the solvent on the rate of oxidation of cobalt acetate
β Scribed by A. A. Kozlov; A. E. Kapustin
- Book ID
- 112458150
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 168 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-5760
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Measurements were made of the value of the lumped kinetic constant k p /k t 0.5 of vinyl acetate in different solvents and with different initiators. This quantity was evaluated using the well-known conversion vs. time approach in dilute solutions using both azo-bis-isobutyronitrile and benzoyl pero
## Abstract During precipitation and calcination at 200Β°C nanocrystalline Co3O4 was obtained with average size crystallites of 13 nm and a well developed specific surface area of 44 m2 gβ1. A small addition of a structural promoter, e.g. Al2O3, increases the specific surface area of the cobalt oxid