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Effect of managanese phthalocyanine on the catalytic activity of cobalt(II) acetate in the homogeneous oxidation of mesitylene

✍ Scribed by Kwaskowska-Chec, E. ;Fried, K. ;Przywarska-Boniecka, H. ;Ziólkowski, J. J.

Book ID
112682738
Publisher
Springer
Year
1975
Tongue
English
Weight
157 KB
Volume
2
Category
Article
ISSN
0133-1736

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Catalytic activity of monomeric and polymeric cobalt(II)-phthalocyanines in sulfide ion oxidation
✍ A. Andreev; V. Ivanova; L. Prahov; I.D. Schopov 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 404 KB

Polymeric cobalt(H)-phthalocyanine exhibited much higher specific catalytic activity in sulfide ion oxidation than the monomeric counterpart. Cobalt disproportionation, 2C02 + \*Co' + + Co3+, was observed with the polymeric phthalocyanine in alkali medium. A concerted process of the oxidation and re