𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of the solvent on enzyme regioselectivity

✍ Scribed by Rubio, Eduardo; Fernandez-Mayorales, Alfonso; Klibanov, Alexander M.


Book ID
120982888
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
302 KB
Volume
113
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


[1,3] and [3,3] rearrangements of 3-amin
✍ Heather K. Dobson; Richard LeBlanc; HΓ©lΓ¨ne Perrier; Corey Stephenson; Teresa R. πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 223 KB

3-Amino-l,5-Hexadienes rearrange under anionic conditions to give a [1,3] product in addition to the [3,3] (Cope) product. With some substrates the regioselectivity of the reaction is strongly influenced by the solvent polarity.