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Effect of the phosphonate group on the reactivity of carbenes. Neighbouring phosphonate group participation

✍ Scribed by Tomioka, Hideo; Hirai, Katsuyuki

Book ID
120034284
Publisher
The Royal Society of Chemistry
Year
1989
Tongue
English
Weight
312 KB
Volume
6
Category
Article
ISSN
0022-4936

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Glycosylidene Carbenes. Part 7. Neighbou
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✍ Yoshikazu Takahashi; Andrea Vasella πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 German βš– 565 KB

## Abstract To demonstrate the neighbouring‐group participation of the 2‐benzyloxy group in the glycosidation of phenols and of strongly acidic alcohols by the diazirine 1, we examined the glycosidation of 4‐nitrophenol, 4‐methoxyphenol, (CF~3~)~2~CHOH, MeOH, and i‐PrOH by the diazirine 11, derived