Effect of the mobility of oxygen in perovskite catalyst on the dynamics of oxidative coupling of methane
โ Scribed by S. I. Reshetnikov; Yu. I. Pyatnitskii; L. Yu. Dolgikh
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 108 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0040-5760
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Addition of trace amounts of H&l to the reactants for metbane oxidative coupling results in the formation of SO, and poisoning of a lanthanum oxide catalyst. Poisoning has little effect on Cx+ selectivity until conversion falls to a low level. The factors controlling catalyst poisoning were found to
The results of oxidative coupling of methane in the presence and absence of catalyst have been compared under the same or similar reaction conditions. The reaction in the presence of catalyst proceeded in steady state, but that in the absence of catalyst showed an induction period. The rate of the l