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Effect of the medium on the properties of the hydrogen bond

โœ Scribed by E. A. Grebneva; K. B. Tolpygo

Publisher
SP MAIK Nauka/Interperiodica
Year
1986
Tongue
English
Weight
594 KB
Volume
26
Category
Article
ISSN
0022-4766

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## Photocyclization of diphenylamine (DPA) in cyclohexane is accelerated by the addition of hydrogen-bonding agents (Q). Laser photolysis studies reveal that Q principally affects the S1 state of DPA. DPA in its S1 state forms a stable hydrogen-bonding complex with Q in which DPA acts as a proton