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Effect of the Medium on the Acid-Base Properties of α-Aminophosphoryl Compounds

✍ Scribed by A. R. Garifzyanov; S. V. Zakharov; G. Kh. Nuriazdanova; F. V. Devyatov; V. L. Galkin; R. A. Cherkasov

Book ID
106522854
Publisher
Springer
Year
2005
Tongue
English
Weight
55 KB
Volume
75
Category
Article
ISSN
1070-3632

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Influence of inductive effects and polar
Influence of inductive effects and polarizability on the acid-base properties of alkyl compounds. Inversion of the alcohol acidity scale
✍ J. Catalán 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 545 KB

The inductive effects and polarizability of a series of 17 alkyl substituents were evaluated in theoretical terms from ab initio calculations for acid-base processes involving the corresponding alkanols. The effects allow one to account for general acid-base processes, both in the gas phase and in s