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Effect of the formation of liquid-crystalline order on parameters of helix-coil conformation transition in poly-γ-benzyl-L-glutamate

✍ Scribed by B.Z Volchek; D.A Medvedeva; A.V Purkina; L.A Ovsyannikova; G.P Vlasov


Book ID
116048556
Publisher
Elsevier Science
Year
1987
Weight
367 KB
Volume
29
Category
Article
ISSN
0032-3950

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## Abstract The thermal helix–coil transition of four samples of poly(γ‐benzyl‐L‐glutamate) in the dioxane–dichloroacetic acid (DCA) mixture was studied by optical rotatory dispersion method. The transition occurred at very high DCA content (97.5% by weight) in this system. The transition parameter