Effect of the Excitation Wavelength on the Ultrafast Charge Recombination Dynamics of Donor−Acceptor Complexes in Polar Solvents
✍ Scribed by Nicolet, Olivier; Banerji, Natalie; Pagès, Stéphane; Vauthey, Eric
- Book ID
- 125953811
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 408 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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The influence of solvent polarity on spectroscopic and thermodynamic properties of molecular electron-donor-acceptor (EDA) complexes is discussed. Analysis of experimental data leads to the conclusion that the ground state of EDA complex is destabilized with increasing polarity of solvent and this i
## Abstract We estimate, at a full quantum‐chemical level, the various molecular parameters governing the rate of photoinduced charge generation and charge recombination in model organic structures containing a donor and an acceptor unit in view of the possible use of such systems in organic solar