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Effect of the composition of the initiating complex acyl halides/aluminium bromide on the cationic polymerization of isobutylene

✍ Scribed by Vladimir B Murachev; Aleksandr I Nesmelov; Valerii S Byrikhin; Elena A Ezhova; Vitalii P Zubov

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
160 KB
Volume
49
Category
Article
ISSN
0959-8103

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## Abstract Influence of the composition of the initiator system employed on polymerization rate, molecular weight and structure of the polymer obtained was studied. At a zinc to aluminium ratio between 0.5 and 1, regular chain structure, and partly isotactic polymer was obtained. The dependence of

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The effect of water on the cationic polymerization of isohutylene by AIEtCI, in n-heptane has been studied. The condition of complete polymerization inhibition is attained a t [H,O] 5 mol/l. Slow polymerization with an induction period is detected a t [H,O]/[AIEtCI,] 5 1. By means of 2,6-DTBP and 0,