✦ LIBER ✦

Effect of the Carboxylate Salt on the CON Bond Homolysis of SG1-Based Alkoxyamines

✍ Scribed by Denis Bertin; Didier Gigmes; Sylvain R. A. Marque; Didier Siri; Paul Tordo; Gregory Trappo

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 728 KB
Volume: 9
Category: Article
ISSN: 1439-4235
DOI: 10.1002/cphc.200700481

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Effect of the Penultimate Unit on the CO

Effect of the Penultimate Unit on the CON Bond Homolysis in SG1-Based Alkoxyamines

✍ Denis Bertin; Pierre-Emmanuel Dufils; Isabelle Durand; Didier Gigmes; Bruno Giov 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB

## Abstract The effect of the penultimate unit on the CON bond homolysis rate constant __k__~d~ was studied for model alkoxyamines. It was shown that the __k__~d~ for fragments containing penultimate and antepenultimate units were nicely predicted by the tri‐parametric relationship developed in __

Chemically Triggered C–ON Bond Homolysis

Chemically Triggered C–ON Bond Homolysis in Alkoxyamines. Part 2: DFT Investigation and Application of the pH Effect on NMP

✍ Elena Bagryanskaya; Paul Brémond; Mariya Edeleva; Sylvain R. A. Marque; Dmitriy 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 627 KB

## Abstract In recent work, a 15‐fold increase in the C–ON bond homolysis rate constant __k__~d~ of 4‐pyridylethyl‐SG1‐based alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C

Nitroxide-Mediated Polymerization of Met

Nitroxide-Mediated Polymerization of Methyl Methacrylate Using an SG1-Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization

✍ Yohann Guillaneuf; Didier Gigmes; Sylvain R. A. Marque; Paul Tordo; Denis Bertin 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 194 KB

## Abstract **Summary:** The nitroxide‐mediated polymerization (NMP) of MMA initiated with a new crowded SG1‐based alkoxyamine was performed. Contrary to the results expected after a kinetic analysis (Fischer's diagram), the polymerization of MMA at 45 °C with SG1 showed only partial control and li

Ionic Conductivity of Lithium Salt/Oligo

Ionic Conductivity of Lithium Salt/Oligo(ethylene oxide)-Based Liquid-Crystal Mixtures: The Effect of Molecular Architecture on the Conduction Process

✍ P. Judeinstein; F. Roussel 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 263 KB 👁 2 views

Effect of varying quaternary ammonium sa

Effect of varying quaternary ammonium salt concentration on the potentiometric properties of some trifluoroacetophenone derivative-based solvent-polymeric membranes

✍ Young Ki Hong; Woo Jin Yoon; Hyun Jun Oh; Young Moo Jun; Hyung-Jung Pyun; Geun S 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 428 KB

Potentiometric properties of carbonate-selective membranes based on some trifluroacetophenone derivatives [e.g., trifluoroacetyl-p-decylbenzene (TFADB), 1,7-bis(4'-trifluoro-acetophenyl)-4-decyl-I ,7-dioxo-2,6-dioxy-heptane (compound I) and i,2-bis(4-trifluoroacetylbenzoyloxymethyl)benzene (compound

Effect of hydrogen bonds on gelation by

Effect of hydrogen bonds on gelation by introduction of carboxyl groups in the free-radical crosslinking copolymerization of butyl methacrylate with 1,6-hexanediol dimethacrylate

✍ Akira Matsumoto; Akiyoshi Ueda; Hiroyuki Aota; Jun-ichi Ikeda 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 45 KB 👁 1 views