Effect of Temperature, Solvent Polarity, and Nature of Lewis Acid on the Rate Constants in the Carbocationic Polymerization of Isobutylene
β Scribed by Sipos, Laszlo; De, Priyadarsi; Faust, Rudolf
- Book ID
- 111938518
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 134 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The effects of three different variables (initiator concentration, polarity of the solvent and reaction temperature) on the rate of dispersion polymerization of styrene in alcohols have been investigated. It was found that the rate of polymerization increases with the initiator (AIBN) concentration
An experimental study was performed to estimate the value of the lumped kinetic constant k p /k t 0.5 . This quantity was evaluated using the well-known conversion vs. time approach in dilute solutions using both azo-bis-isobutyronitrile and benzoyl peroxide (AIBN and BPO), and two different solvent
Measurements were made of the value of the lumped kinetic constant k p /k t 0.5 of vinyl acetate in different solvents and with different initiators. This quantity was evaluated using the well-known conversion vs. time approach in dilute solutions using both azo-bis-isobutyronitrile and benzoyl pero
## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__βpropylβpyridylmethanimine (NPPMI) and __N__βoctylβpyridylmethanimine (NOP