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Effect of Surfactant Concentration on Particle Nucleation in Emulsion Polymerization of n -Butyl Methacrylate

✍ Scribed by Krishnan, Sitaraman; Klein, Andrew; El-Aasser, Mohamed S.; Sudol, E. David


Book ID
127298714
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
94 KB
Volume
36
Category
Article
ISSN
0024-9297

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Based on the coagulative particle nucleation mechanism, a two-step model has been developed for the semi-batch surfactant-free emulsion polymerization of butyl acrylate, or butyl acrylate in the presence of a small amount of acrylic acid. During Stage 1, precursor particles are Ðrst formed by phase