Effect of sulfuric acid concentration on the rates of hydrolysis of ethyl benzoate ethyl thiolbenzoate, and ethyl thionbenzoate
โ Scribed by Edward, John T.; Wong, Sin Cheong
- Book ID
- 125950764
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 535 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
From the mechanistic standpoint alkaline hydrolysis of substituted benzoates has repeatedly been studied carefully and much rate data in various conditions are now available (l-3). Nowever, all these measurements were carried out in organic solvents containing relatively small amounts of water.
In our last pa&u (I) it ras reported that in the olkaline'hydrolysis of substituted ethyl bensoates the change of the solvent from' 85 %(rt.) aqueous ethanol to 3 %(rt.) aqueous ethanol caused 5C times increase in the rate of the unsubstituted compound and decrease to a half in the Bammett p value,