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The alkaline hydrolysis of substituted ethyl benzoates. The additive effects of substituents

✍ Scribed by Jones, Brynmor ;Robinson, John


Book ID
111888772
Publisher
The Royal Society of Chemistry
Year
1955
Weight
576 KB
Category
Article
ISSN
0368-1769

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πŸ“œ SIMILAR VOLUMES


Ortho effects III. Rates of alkaline hyd
✍ Masaru Hojo; Masamori Utaka; Zen-ichi Xoshida πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 French βš– 206 KB

From the mechanistic standpoint alkaline hydrolysis of substituted benzoates has repeatedly been studied carefully and much rate data in various conditions are now available (l-3). Nowever, all these measurements were carried out in organic solvents containing relatively small amounts of water.

Ortho effects IV. Rates of alkaline hydr
✍ Masaru Hojo; Masanori Utaka; Zen-ichi Yoshida πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 French βš– 235 KB

In our last pa&u (I) it ras reported that in the olkaline'hydrolysis of substituted ethyl bensoates the change of the solvent from' 85 %(rt.) aqueous ethanol to 3 %(rt.) aqueous ethanol caused 5C times increase in the rate of the unsubstituted compound and decrease to a half in the Bammett p value,