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Effect of Substituents on the Silicon Atom on Etherification of Organochlorosilanes with Ethanol

โœ Scribed by E. A. Chernyshev; Z. V. Belyakova; E. A. Komarov; V. G. Bykovchenko


Book ID
110319428
Publisher
Springer
Year
2001
Tongue
English
Weight
35 KB
Volume
71
Category
Article
ISSN
1070-3632

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Migratory aptitude of substituents on si
โœ Akira Oku; Toshiyuki Miki; Yasuyoshi Ose ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 291 KB ๐Ÿ‘ 1 views

Photolysis of (dimethylphenylsilyl)(trimethylsilyl)diazomethane in t-BuOH yielded three different t-BuOsubstituted (silylalkyl)silanes. The migratory aptitude of substituents from the silicon atoms to the carbenic center was found to be in the order Ph:Me (on phenyl-substituted Si):Me (on TMS)=3.8: