## Abstract Pyridiniumchlorochromate (PCC) oxidizes aniline and substituted anilines except nitro anilines smoothly in chlorobenzeneβnitrobenzene mixtures in the presence of dichloroacetic acid. The reaction has unit dependence on each of the aniline, PCC, and dichloroacetic acid concentrations. El
β¦ LIBER β¦
Effect of substituent on the mechanism of oxidation of anilines by acidic iodate. A kinetic study
β Scribed by Manikyamba, P. ;Sundaram, E. V.
- Book ID
- 112695741
- Publisher
- Springer
- Year
- 1985
- Tongue
- English
- Weight
- 221 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0133-1736
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## Abstract Oxidation of aromatic amines (substrate) by peroxomonosulphate (PMS) in phthalate buffers at various temperatures revealed firstβorder dependence on [PMS] as well as [Substrate]. Rate of oxidation was found to increase with an increase in pH as well as dielectric constant (D) of the med