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Effect of specific adsorption of anions on polarographic reduction

✍ Scribed by Giulia Grandi; Roberto Andreoli; Giovanna Battistuzzi Gavioli


Publisher
Elsevier Science
Year
1970
Weight
202 KB
Volume
27
Category
Article
ISSN
0022-0728

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✦ Synopsis


Ecu -E o = ( -i. 165 __+ 0.030) V and 2.3 RT/F = (187_ 14) mV Moreover, by considering the values of AG*/nF for the pure metal chlorides, we can observe that the activity coefficient fM is near to unity for the noble metals, leading us to suppose that the solution of their chlorides is nearly "perfect", while for the others the formation of complexes can be postulated (fu ~ 1).


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