Effect of Solvent upon CH···O Hydrogen Bonds with Implications for Protein Folding
✍ Scribed by Scheiner, Steve; Kar, Tapas
- Book ID
- 127072015
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 193 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The X-ray crystal structures of the complexes C6H5CHOoBF31 and H2C=C(CH3)CHO.BF32 reveal that the BF3 is coordinated to the oxygen lone pair which is syn to the formyl proton and, further, that the formyl proton and one B-F bond are in plane (eclipsed) with respect to the C-O-B triad, as shown in 1.
## Abstract We prepared a set of about 2000 α‐helices from a relational database of high‐resolution three‐dimensional structures of globular proteins, and identified additional main chain __i__ ← __i__+3 hydrogen bonds at the ends of the helices (i.e., where the hydrogen bonding potential is not fu