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Effect of Solvent on the Claisen Rearrangement of Allyl Vinyl Ether Using ab initio Continuum Methods

โœ Scribed by Davidson, Mark M.; Hillier, Ian H.; Hall, Richard J.; Burton, Neil A.


Book ID
127016055
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
440 KB
Volume
116
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


The Claisen rearrangement of allyl vinyl
โœ Mark M. Davidson; Ian H. Hillier; Mark A. Vincent ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 348 KB

Structures of the reactant and transition state of the Claisen rearrangement of allyl vinyl ether are obtained at a higher level of electron correlation than previously reported, and yield a closer prediction of the activation barrier. The transition state is predicted to be more dissociative in aqu