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Substituent effects on the aliphatic Claisen rearrangement. 1. Synthesis and rearrangement of cyano-substituted allyl vinyl ethers

✍ Scribed by Burrows, Cynthia J.; Carpenter, Barry K.

Book ID
126999346
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
272 KB
Volume
103
Category
Article
ISSN
0002-7863

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Synthesis and Lewis acid catalyzed Clais
Synthesis and Lewis acid catalyzed Claisen rearrangement of 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers
✍ Hannes Helmboldt; Martin Hiersemann πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 245 KB

Allyl vinyl ethers containing an acceptor function in the 2-position are useful substrates for the Lewis acid-catalyzed Claisen rearrangement. The first synthesis of acyclic 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers is reported. The Lewis acid catalyzed Claisen rearrangement of these ally