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Effect of solvent composition on dimerization rate of 2,6-diphenyl-4-methoxyphenoxyl radicals

✍ Scribed by I. V. Khudyakov; T. A. Kokrashvili; P. P. Levin; V. A. Kuz'min

Book ID: 112438554
Publisher: Springer
Year: 1977
Tongue: English
Weight: 285 KB
Volume: 26
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00923658

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## Abstract The kinetics of oxidation of 3‐R‐2,6‐diphenyl‐piperidin‐4‐ones (where R = H, Me, Et, and __i__‐Pr) by quinolinium chlorochromate has been studied under pseudo‐first‐order conditions in different pure (protic and aprotic) solvents. The rate data is correlated with different solvent param