The dipole moments of CH379Br, CHsI and CD31 have been accurately measured by Doppler-free microwave Stark spectroscopy. The results are: P(CH~'~B~) =1.8203(4) D; .&CH,I)= 1.6406(4) D and p(CD,I)=1.6507(4) D. The dipole moments of the methyl halides CH3X (X = F, Cl, Br, I) are shown to be smaller th
Effect of soil physical factors on methyl iodide and methyl bromide
β Scribed by Zhang, Wenming; McGiffen, Milton E.; Becker, J. Ole; Ohr, Howard D.; Sims, James J.; Campbell, Steven D.
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 397 KB
- Volume
- 53
- Category
- Article
- ISSN
- 1526-498X
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β¦ Synopsis
Production and importation of methyl bromide is scheduled to be banned by 2001. Methyl iodide was evaluated as a possible replacement soil fumigant. The e β ects of soil moisture, temperature, soil texture and fumigation time on the efficacy of methyl iodide for the control of two common weeds, Abutilon theophrasti and L olium multiΓorum, were characterized and compared with those of methyl bromide. The optimal soil moisture for methyl iodide to kill both weed species in sandy soils was 14% water content (w/w). Greater efficacy was obtained when the temperature during fumigation was above 20Β‘C. Compared to methyl bromide, the efficacy of methyl iodide was more consistent in di β erent soils. Time to 100% mortality of weeds was 24 h for methyl iodide fumigation and 36 h for methyl bromide when 200 kM of fumigant was used. On a molar basis methyl iodide was consistently more e β ective than methyl bromide across the range of environmental factors tested. In terms of application technology and spectrum of activity, methyl bromide can be directly replaced by methyl iodide.
1998 SCI (
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## Abstract The gaseous diffusion coefficients of methyl bromide (CH~3~Br) and methyl iodide (CH~3~I) into dry air, nitrogen, and oxygen have been measured in the temperature range 303β453 K and at atmospheric pressure via the Taylor dispersion method. Both for methyl bromide and methyl iodide, the
## Abstract Fumigation of wheat with methyl bromide causes a change in the polyacrylamide gel, isoelectric focusing profile of esterase proteins from aqueous extracts of wheat. The significance of this effect is discussed in the light of known reactions of methyl bromide in stored products.