## Abstract Stereoselective synthesis is attracting more and more attention. Successful stereoselective syntheses require the availability of reactions of known stereochemistry which give maximum yields of the desired products. This is particularly so with reactions proceeding __via__ cyclic transi
✦ LIBER ✦
Effect of pressure on the rate of [3,3]-sigmatropic rearrangements
✍ Scribed by G. A. Stashina; E. M. Vasil'vitskaya; G. D. Gamalevich; B. S. Él'yanov; É. P. Serebryakov; V. M. Zhulin
- Book ID
- 112444259
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 436 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1573-9171
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Treatment of allylic alcohols with thiophosgene and pyridine gives thiolo chloroformates directly at room temperature, presumably via very rapid [3,3] sigmatropic rearrangements of thiono chloroformates. Synthesis of allyl thiono chloroformate from allyl alcohol, sodium hydride and thiophosgene at l