Treatment of allylic alcohols with thiophosgene and pyridine gives thiolo chloroformates directly at room temperature, presumably via very rapid [3,3] sigmatropic rearrangements of thiono chloroformates. Synthesis of allyl thiono chloroformate from allyl alcohol, sodium hydride and thiophosgene at l
β¦ LIBER β¦
[3,3]-Sigmatropic rearrangement of allylic dialkylthiocarbamates
β Scribed by Hackler, R. E.; Balko, T. W.
- Book ID
- 126889825
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 587 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-3263
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