𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of pressure on the decomposition of 2-tert-butyl peroxide in solution

✍ Scribed by V. M. Zhulin; I. Khuéidzha; E. B. Kabotyanskaya; Yu. D. Koreshkov

Book ID
112448967
Publisher
Springer
Year
1990
Tongue
English
Weight
301 KB
Volume
39
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Decomposition of di-tert-butyl nitroxide
Decomposition of di-tert-butyl nitroxide in aqueous solutions
✍ T. Cáceres; C. Urzúa; E. A. Lissi 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB

Di-tert-butyl nitroxide (DTBN) decomposes in aqueous solutions producing 2-methyl-2-nitroso propane (MNP) and tert-butanol. The process is acid catalyzed, it is of second order in DTBN, and takes place with a rate constant of (1.0 2 0.1) M-\* s-'. The reaction is also catalyzed by the anionic surfac