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Effect of Penultimate Unit on the Activation Process in ATRP

✍ Scribed by Nanda, Ajaya Kumar; Matyjaszewski, Krzysztof

Book ID: 127000265
Publisher: American Chemical Society
Year: 2003
Tongue: English
Weight: 59 KB
Volume: 36
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma035219n

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## Abstract The effect of the penultimate unit on the CON bond homolysis rate constant __k__~d~ was studied for model alkoxyamines. It was shown that the __k__~d~ for fragments containing penultimate and antepenultimate units were nicely predicted by the tri‐parametric relationship developed in __