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Temperature Effect on Activation Rate Constants in ATRP: New Mechanistic Insights into the Activation Process

โœ Scribed by Seeliger, Florian; Matyjaszewski, Krzysztof


Book ID
126780594
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
957 KB
Volume
42
Category
Article
ISSN
0024-9297

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## Abstract Summary: The effect of [L]/[Cu^I^] ratio, ligand, the choice of solvent and temperature on the activation rate constants in ATRP with catalyst complexes formed with two pyridylmethanimine ligands [PMI, i.e., __N__โ€propylโ€pyridylmethanimine (NPPMI) and __N__โ€octylโ€pyridylmethanimine (NOP