𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Effect of nucleophile on the activation parameters of transesterification of 4-nitrophenyl benzoates

✍ Scribed by I. A. Os’kina; V. M. Vlasov

Book ID
111465289
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
211 KB
Volume
46
Category
Article
ISSN
1070-4280

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetic study of the reactions of p-nitr
Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles
✍ Shuchi Tiwari; Sancheeta Kolay; Kallol K. Ghosh; Kamil Kuca; Jan Marek 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB

## Abstract The reactions of __p__‐nitrophenyl acetate (PNPA) and __p__‐nitrophenyl benzoate (PNPB) with α‐nucleophile oximates, that is, butane 2,3‐dione monoximate, pralidoximate, and other oximates have been studied in the presence of different cationic surfactants. The first‐order rate constant

The effect of acyl substituents on the α
The effect of acyl substituents on the α-effect: contrasting α-effect profiles for reactions of 4-nitrophenyl substituted benzoates with neutral and anionic nucleophiles
✍ Ik-Hwan Um; Hyun-Joo Han; Eun-Kyung Chung 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 80 KB

The magnitude of the a-effect for reactions of 4-nitrophenyl substituted benzoates with a pair of anionic nucleophiles is independent of the electronic nature of the acyl substituent, while the one for the corresponding reactions with a pair of neutral nucleophiles increases as the acyl substituent