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Kinetic study of the reactions of p-nitrophenyl acetate and p-nitrophenyl benzoate with oximate nucleophiles

✍ Scribed by Shuchi Tiwari; Sancheeta Kolay; Kallol K. Ghosh; Kamil Kuca; Jan Marek

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
128 KB
Volume
41
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The reactions of p‐nitrophenyl acetate (PNPA) and p‐nitrophenyl benzoate (PNPB) with α‐nucleophile oximates, that is, butane 2,3‐dione monoximate, pralidoximate, and other oximates have been studied in the presence of different cationic surfactants. The first‐order rate constant increases with increasing surfactant concentration. The extent of acceleration is dependent on the head group structure of surfactants. The PNPA is more reactive than PNPB toward all the nucleophiles at higher concentration of surfactants. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 41: 57–64, 2009

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