## Abstract Delocalisation of the nitrogen lone electron pair by an acyl and acylvinylogue group simultaneously, results in a lowering of both CN rotational barriers. MeC(O)CBrCHNMe~2~ and MeC(O)C(OCOMe)CHNMe~2~ exhibit restricted rotation around what is formally a double bond CC.
Effect of nitrogen substituents on CN rotational barriers in enamine derivatives
✍ Scribed by Marcel Azzaro; Serge Geribaldi; Bruno Videau
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 438 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0749-1581
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