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ChemInform Abstract: First Application of Amino-TADDOL Derivatives in Enantioselective Addition of Diethylzinc to Aryl Aldehydes: Effect of Substituents on the Nitrogen Atom.

โœ Scribed by Chang-Tao Qian; Fei-Feng Gao; Jie Sun


Publisher
John Wiley and Sons
Year
2000
Weight
31 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dramatic Temperatur
โœ Huichang Zhang; Kin Shing Chan ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 2 views

Dramatic Temperature Effect in Asymmetric Catalysis in the Enantioselective Addition of Diethylzinc to Aldehydes. -The enantioselectivity of the addition of Et 2 Zn to aryl aldehydes in the presence of catalytic amounts of a chiral pyridyl-phenol ((S)-MPBP) is found to depend heavily on temperature