Effect of molecular weight and branch content on the creep behavior of oriented polyethylene

✍ Scribed by P. A. O'Connell; M. J. Bonner; R. A. Duckett; I. M. Ward

• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 126 KB
• Volume: 89
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.12434

✦ Synopsis

Abstract

Creep studies were carried out on a range of homopolymers and copolymers of polyethylene with well‐defined molecular weight and branch content. The creep data were analyzed in terms of two thermally activated processes acting in parallel and the effects of molecular weight and branch content are discussed. It is shown that increasing either the number‐average molecular weight or the weight‐average molecular weight gives improved creep behavior at all stress levels. The introduction of butyl branches leads to lower creep at low‐stress levels but can give rise to higher creep at high stress. Plots of the equilibrium log~10~(strain rate) versus stress at fixed draw ratio (strain) can be used to define sections through a unique true stress/true strain/strain rate surface for each material. These creep results have an additional value in terms of the link between slow crack propagation (SCG) in polyethylene and fibril creep, confirming the proposal made elsewhere that SCG can be quantified in terms of creep to failure across the true stress/true strain/strain rate surface. © 2003 Wiley Periodicals, J Appl Polym Sci 89: 1663–1670, 2003