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Ultradrawing behavior of one- and two-stage drawn gel films of ultrahigh molecular weight polyethylene and low molecular weight polyethylene blends

✍ Scribed by Jen-Taut Yeh; Sheng-Shan Chang; Meng-shung Yen


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
213 KB
Volume
70
Category
Article
ISSN
0021-8995

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✦ Synopsis


The ultradrawing behavior of gel films of plain ultrahigh molecular weight polyethylene (UHMWPE) and UHMWPE/low molecular weight polyethylene (LMWPE) blends was investigated using one-and two-stage drawing processes. The drawability of these gel films were found to depend significantly on the temperatures used in the one-and two-stage drawing processes. The critical draw ratio ( c ) of each gel film prepared near its critical concentration was found to approach a maximum value, when the gel film was drawn at an ''optimum'' temperature ranging from 95 to 105Β°C. At each drawing temperature, the one-stage drawn gel films exhibited an abrupt change in their birefringence and thermal properties as their draw ratios reached about 40. In contrast, the critical draw ratios of the two-stage drawn gel films can be further improved to be higher than those of the corresponding single-stage drawn gel films, in which the two-stage drawn gel films were drawn at another ''optimum'' temperature in the second drawing stage after they had been drawn at 95Β°C to a draw ratio of 40 in the first drawing stage. These interesting phenomena were investigated in terms of the reduced viscosities of the solutions, thermal analysis, birefringence, and tensile properties of the drawn and undrawn gel films.


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