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Effect of microemulsions on the Diels-Alder reaction: endo/exo ratios in the reaction of cyclopentadiene and methyl methacrylate

✍ Scribed by Gonzalez, Alvaro; Holt, Smith L.


Book ID
120454794
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
428 KB
Volume
47
Category
Article
ISSN
0022-3263

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The endo/exo stereoselectivity of the Diels-Alder cycloaddition between cyclopentadiene and 3-crotonoyl-2-oxazolidinone catalysed by Et 2 AlCl is temperature-and solvent-dependent. Eyring plots of ln(endo/exo) versus 1/T show different inversion temperatures (T inv ) depending on the reaction solven