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Ab Initio Study of Endo / Exo and Diastereofacial Selectivities in Diels−Alder Reactions between Chiral Butenolides and Cyclopentadiene

✍ Scribed by Sbai, Abdelouahid; Vicenç, ; Oliva, Antonio

Book ID
127382384
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
253 KB
Volume
61
Category
Article
ISSN
0022-3263

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endo-exo Selectivity in Diels-Alder cycloadditions of several o-quinodimethanes (1-4) with acrylonitrile, 2-(5H)-furanone and N-methylmaleimide has been investigated in acetonitrile solution. Transition structures of the cycloaddition of the parent o-QDM (1), (E,E)-1,8-dimethyl-o-QDM (2), isoindene