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Effect of Micro and Bulk Solvation on the Mechanism of Nucleophilic Substitution at Sulfur in Disulfides

โœ Scribed by Hayes, Joseph M.; Bachrach, Steven M.


Book ID
120566407
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
537 KB
Volume
107
Category
Article
ISSN
1089-5639

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๐Ÿ“œ SIMILAR VOLUMES


Mechanisms of substitution reactions at
โœ John L. Kice; Giancarlo Guaraldi ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 258 KB

In investigating further the role of a sulfinyl sulfone (I) as an intermediate in the disproportion&ion of an aryl sulfinic acid (1,2) we have measured the rate of hydrolysis of Ia (eq. 1) in acetic acid-l% water as solvent. In the course of this work we have discovered that the rate